In addition, it can be seen in Tables 1 and 3 that at the same concentration of fullerene (Φ=0.001) the value of tanα is higher for the film formed of o-xylene than for the film formed of toluene. This can be explained by the fact that the solubility of fullerenes in o-xylene is higher than in toluene, what correlates with the findings of Zhou et al (1997). It appears that in toluene solution the fullerene molecules are in the form of clusters, which does not ensure uniform distribution of the nanoparticles in the composite film during its formation of solution.
Note also, we had preliminary experiments with films containing fullerene that were fabricated by the casting of aliphatic compound — chloroform. The results of chemiluminescent analysis and spectrophotometry for serum samples after exposure of both original polystyrene film and composite films regardless of the fullerenes content were approximate to controls. This again emphasizes the significance of the medium in which the films were fabricated.
In conclusion, our investigation proved that polystyrene/fullerene nanocomposites have the ability to activate lipid peroxidation in blood serum. Moreover, the possibility of such activation depends on the composite forming conditions.
Acknowledgments
The study was supported by the Russian Foundation for Basic Research (project no. 12-03-97528-a).
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